Nowadays,we mainly depend on fossil fuels as our primary energy, but it can bring serious energy crisis, enviromnental pollution and health problems,Since the energy crisis in the world, it is of paramount importance to develop the so-called clean energy or renewable energy, especially hydrogen energy, Hydrogen is a clean, renewable, high efficieney, and high heat value energy form ,it is considered as an optimum alternative of fossil fuel in the future. There have many hydrogen production methods, except biological hydrogen production offer distinct advantages for hydrogen production such as operation under mild conditions andhigh conversion efficieney.